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α‐Thianthrenium Carbonyl Species: The Equivalent of an α‐Carbonyl Carbocation

Here we report an α‐thianthrenium carbonyl species, as the equivalent of an α‐carbonyl carbocation, which is generated by the radical conjugate addition of a trifluoromethyl thianthrenium salt to Michael acceptors. The reactivity allows for the synthesis of C(α)‐tetrasubstituted α‐ and β‐amino acid...

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Detalles Bibliográficos
Autores principales: Jia, Hao, Ritter, Tobias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804271/
https://www.ncbi.nlm.nih.gov/pubmed/35895980
http://dx.doi.org/10.1002/anie.202208978