Heterolytic O−O Bond Cleavage Upon Single Electron Transfer to a Nonheme Fe(III)−OOH Complex

The one‐electron reduction of the nonheme iron(III)‐hydroperoxo complex, [Fe(III)(OOH)(L(5) (2))](2+) (L(5) (2)=N‐methyl‐N,N’,N’‐tris(2‐pyridylmethyl)ethane‐1,2‐diamine), carried out at −70 °C results in the release of dioxygen and in the formation of [Fe(II)(OH)(L(5) (2))](+) following a bimolecula...

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Detalles Bibliográficos
Autores principales: Bohn, Antoine, Sénéchal‐David, Katell, Rebilly, Jean‐Noël, Herrero, Christian, Leibl, Winfried, Anxolabéhère‐Mallart, Elodie, Banse, Frédéric
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804275/
https://www.ncbi.nlm.nih.gov/pubmed/35735122
http://dx.doi.org/10.1002/chem.202201600

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804275/
https://www.ncbi.nlm.nih.gov/pubmed/35735122
http://dx.doi.org/10.1002/chem.202201600

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