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Heterolytic O−O Bond Cleavage Upon Single Electron Transfer to a Nonheme Fe(III)−OOH Complex
The one‐electron reduction of the nonheme iron(III)‐hydroperoxo complex, [Fe(III)(OOH)(L(5) (2))](2+) (L(5) (2)=N‐methyl‐N,N’,N’‐tris(2‐pyridylmethyl)ethane‐1,2‐diamine), carried out at −70 °C results in the release of dioxygen and in the formation of [Fe(II)(OH)(L(5) (2))](+) following a bimolecula...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804275/ https://www.ncbi.nlm.nih.gov/pubmed/35735122 http://dx.doi.org/10.1002/chem.202201600 |