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Chemo‐ and Site‐Selective Electro‐Oxidative Alkane Fluorination by C(sp(3))−H Cleavage

Electrochemical fluorinations of C(sp(3))−H bonds with a nucleophilic fluoride source have been accomplished in a chemo‐ and site‐selective fashion, avoiding the use of electrophilic F(+) sources and stoichiometric oxidants. The introduced metal‐free strategy exhibits high functional group tolerance...

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Detalles Bibliográficos
Autores principales: Stangier, Maximilian, Scheremetjew, Alexej, Ackermann, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804291/
https://www.ncbi.nlm.nih.gov/pubmed/35844078
http://dx.doi.org/10.1002/chem.202201654