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Chemo‐ and Site‐Selective Electro‐Oxidative Alkane Fluorination by C(sp(3))−H Cleavage
Electrochemical fluorinations of C(sp(3))−H bonds with a nucleophilic fluoride source have been accomplished in a chemo‐ and site‐selective fashion, avoiding the use of electrophilic F(+) sources and stoichiometric oxidants. The introduced metal‐free strategy exhibits high functional group tolerance...
Autores principales: | Stangier, Maximilian, Scheremetjew, Alexej, Ackermann, Lutz |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804291/ https://www.ncbi.nlm.nih.gov/pubmed/35844078 http://dx.doi.org/10.1002/chem.202201654 |
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