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The Preparation of Diaryl Sulfoxinium Triflates and Their Application in Palladium‐Catalyzed Cross‐Coupling Reactions

Treatment of N‐methyl‐S,S‐diaryl sulfoximines with methyl trifluoromethanesulfonate provides bench‐stable sulfoxinium salts in excellent yields. Applying them in Sonogashira‐, Heck‐ and Suzuki‐type cross‐coupling reactions leads to the corresponding products by sequential C−S bond cleavage and C−C b...

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Detalles Bibliográficos
Autores principales: Wang, Chenyang, Wang, Xianliang, Kong, Deshen, Truong, Khai‐Nghi, Rissanen, Kari, Bolm, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804342/
https://www.ncbi.nlm.nih.gov/pubmed/35947778
http://dx.doi.org/10.1002/asia.202200828