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Structural Variety of Niobium(V) Polyoxo Clusters Obtained from the Reaction with Aromatic Monocarboxylic Acids: Isolation of {Nb(2)O}, {Nb(4)O(4)} and {Nb(8)O(12)} Cores

The reactivity of aryl monocarboxylic acids (benzoic, 1‐ or 2‐naphtoic, 4’‐methylbiphenyl‐4‐carboxylic, and anthracene‐9‐carboxylic acids) as complexing agents for the ethoxide niobium(V) (Nb(OEt)(5) precursor has been investigated. A total of eight coordination complexes were isolated with distinct...

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Detalles Bibliográficos
Autores principales: Andriotou, Despoina, Duval, Sylvain, Volkringer, Christophe, Trivelli, Xavier, Shepard, William E., Loiseau, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804397/
https://www.ncbi.nlm.nih.gov/pubmed/35866432
http://dx.doi.org/10.1002/chem.202201464