Aerobic/Room‐Temperature‐Compatible s‐Block Organometallic Chemistry in Neat Conditions: A Missing Synthetic Tool for the Selective Conversion of Nitriles into Asymmetric Alcohols

Highly‐efficient and selective one‐pot/two‐step modular double addition of different highly polar organometallic reagents (RLi/RMgX) to nitriles en route to asymmetric tertiary alcohols (without the need for isolation/purification of any halfway reaction intermediate) has been studied, for the first...

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Detalles Bibliográficos
Autores principales: Elorriaga, David, Carrillo‐Hermosilla, Fernando, Parra‐Cadenas, Blanca, Antiñolo, Antonio, García‐Álvarez, Joaquín
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804429/
https://www.ncbi.nlm.nih.gov/pubmed/35904929
http://dx.doi.org/10.1002/cssc.202201348

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804429/
https://www.ncbi.nlm.nih.gov/pubmed/35904929
http://dx.doi.org/10.1002/cssc.202201348

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