C−H and Si−H Activation Reactions at Ru/Ga Complexes: A Combined Experimental and Theoretical Case Study on the Ru−Ga Bond

Treatment of [Ru(COD)(MeAllyl)(2)] and [Ru(COD)(COT)] with GaCp* under hydrogenolytic conditions leads to reactive intermediates which activate Si−H or C−H bonds, respectively. The product complexes [Ru(GaCp*)(3)(SiEt(3))H(3)] (1) and [Ru(GaCp*)(3)(C(7)H(7))H(3)] (2) are formed with HSiEt(3) or with...

Descripción completa

Detalles Bibliográficos
Autores principales: Muhr, Maximilian, Bühler, Raphael, Liang, Hao, Gilch, Jonas, Jandl, Christian, Kahlal, Samia, Saillard, Jean‐Yves, Gemel, Christian, Fischer, Roland A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804459/
https://www.ncbi.nlm.nih.gov/pubmed/35748293
http://dx.doi.org/10.1002/chem.202200887

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804459/
https://www.ncbi.nlm.nih.gov/pubmed/35748293
http://dx.doi.org/10.1002/chem.202200887

Ejemplares similares