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Water Reduction and Dihydrogen Addition in Aqueous Conditions With ansa‐Phosphinoborane

Ortho‐phenylene‐bridged phosphinoborane (2,6‐Cl(2)Ph)(2)B‐C(6)H(4)‐PCy(2) 1 was synthesized in three steps from commercially available starting materials. 1 reacts with H(2) or H(2)O under mild conditions to form corresponding zwitterionic phosphonium borates 1‐H(2) or 1‐H(2)O. NMR studies revealed...

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Detalles Bibliográficos
Autores principales: Sorochkina, Kristina, Chernichenko, Konstantin, Zhivonitko, Vladimir V., Nieger, Martin, Repo, Timo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804508/
https://www.ncbi.nlm.nih.gov/pubmed/35861909
http://dx.doi.org/10.1002/chem.202201927