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Transformations of Strained Three‐Membered Rings a Common, Yet Overlooked, Motif in Heavy‐Atom Tunneling Reactions

Quantum mechanical tunneling has long been recognized as an important phenomenon when considering transformations dominated by a lightweight hydrogen atom. Tunneling of heavier atoms like carbon, initially dismissed as negligible, has seen a quickly increasing number of computationally predicted and...

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Detalles Bibliográficos
Autor principal: Schleif, Tim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804509/
https://www.ncbi.nlm.nih.gov/pubmed/35762788
http://dx.doi.org/10.1002/chem.202201775