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Catalysis by [Ga(4)L(6)](12−) Metallocage on the Nazarov Cyclization: The Basicity of Complexed Alcohol is Key
The Nazarov cyclization is investigated in solution and within K(12)[Ga(4)L(6)] supramolecular organometallic cage by means of computational methods. The reaction needs acidic condition in solution but works at neutral pH in the presence of the metallocage. The reaction steps for the process are ana...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804567/ https://www.ncbi.nlm.nih.gov/pubmed/35859038 http://dx.doi.org/10.1002/chem.202201792 |