Spontaneous Decomposition of an Extraordinarily Twisted and Trans‐Bent Fully‐Phosphanyl‐Substituted Digermene to an Unusual Ge(I) Cluster

Ditetrelenes R(2)E=ER(2) (E=Si, Ge, Sn, Pb) substituted by multiple N/P/O/S‐donor groups are extremely rare due to their propensity to disaggregate into their tetrylene monomers R(2)E. We report the synthesis of the first fully phosphanyl‐substituted digermene {(Mes)(2)P}(2)Ge=Ge{P(Mes)(2)}(2) (3, M...

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Detalles Bibliográficos
Autores principales: Izod, Keith, Liu, Mo, Evans, Peter, Wills, Corinne, Dixon, Casey M., Waddell, Paul G., Probert, Michael R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804623/
https://www.ncbi.nlm.nih.gov/pubmed/35946808
http://dx.doi.org/10.1002/anie.202208851

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804623/
https://www.ncbi.nlm.nih.gov/pubmed/35946808
http://dx.doi.org/10.1002/anie.202208851

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