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Spontaneous Decomposition of an Extraordinarily Twisted and Trans‐Bent Fully‐Phosphanyl‐Substituted Digermene to an Unusual Ge(I) Cluster
Ditetrelenes R(2)E=ER(2) (E=Si, Ge, Sn, Pb) substituted by multiple N/P/O/S‐donor groups are extremely rare due to their propensity to disaggregate into their tetrylene monomers R(2)E. We report the synthesis of the first fully phosphanyl‐substituted digermene {(Mes)(2)P}(2)Ge=Ge{P(Mes)(2)}(2) (3, M...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804623/ https://www.ncbi.nlm.nih.gov/pubmed/35946808 http://dx.doi.org/10.1002/anie.202208851 |