Cargando…

Entropy‐Induced Selectivity Switch in Gold Catalysis: Fast Access to Indolo[1,2‐a]quinolines

New N‐heterocyclic compounds for organic functional materials and their efficient syntheses are highly demanded. A surprising entropy‐induced selectivity switch in the gold‐catalyzed intramolecular hydroarylation of 2‐ethynyl N‐aryl indoles was found and its exploitation led to straightforward synth...

Descripción completa

Detalles Bibliográficos
Autores principales: Heckershoff, Robin, May, Garrett, Däumer, Janika, Eberle, Lukas, Krämer, Petra, Rominger, Frank, Rudolph, Matthias, Mulks, Florian F., Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804639/
https://www.ncbi.nlm.nih.gov/pubmed/35699266
http://dx.doi.org/10.1002/chem.202201816