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Terminal N(2) Dissociation in [(PNN)Fe(N(2))](2)(μ‐N(2)) Leads to Local Spin‐State Changes and Augmented Bridging N(2) Activation
Nitrogen fixation at iron centres is a fundamental catalytic step for N(2) utilisation, relevant to biological (nitrogenase) and industrial (Haber‐Bosch) processes. This step is coupled with important electronic structure changes which are currently poorly understood. We show here for the first time...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804668/ https://www.ncbi.nlm.nih.gov/pubmed/35916757 http://dx.doi.org/10.1002/chem.202202172 |