Cargando…

Terminal N(2) Dissociation in [(PNN)Fe(N(2))](2)(μ‐N(2)) Leads to Local Spin‐State Changes and Augmented Bridging N(2) Activation

Nitrogen fixation at iron centres is a fundamental catalytic step for N(2) utilisation, relevant to biological (nitrogenase) and industrial (Haber‐Bosch) processes. This step is coupled with important electronic structure changes which are currently poorly understood. We show here for the first time...

Descripción completa

Detalles Bibliográficos
Autores principales:	Regenauer, Nicolas I., Wadepohl, Hubert, Roşca, Dragoş‐Adrian
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804668/ https://www.ncbi.nlm.nih.gov/pubmed/35916757 http://dx.doi.org/10.1002/chem.202202172

Ejemplares similares

A Redox‐Active Heterobimetallic N‐Heterocyclic Carbene Based on a Bis(imino)pyrazine Ligand Scaffold
por: Regenauer, Nicolas I., et al.
Publicado: (2020)

catena-Poly[[(2,2′-bipyidine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-dicopper(I)]-μ-bromido-[(2,2′-bipyidine-2κ(2) N,N′)-μ-cyanido-1:2κ(2) N:C-dicopper(I)]-μ-cyanido-κ(2) N:C]
por: Gu, Jia, et al.
Publicado: (2012)

catena-Poly[sodium-μ(2)-(N,N,N′,N′-tetramethylethane-1,2-diamine)-κ(2) N:N′-sodium-bis[μ(2)-bis(trimethylsilyl)azanido-κ(2) N:N]]
por: Kennedy, Alan R., et al.
Publicado: (2012)

catena-Poly[[μ(3)-hydroxido-tetra-μ(2)-pyridazine-1:2κ(4) N:N′;1:3κ(2) N:N′;2:3κ(2) N:N′-tetrakis(selenocyanato)-1κN,2κN,3κ(2) N-trizinc(II)]-μ-cyanido-1:2′κ(2) C:N]
por: Reinert, Thorben, et al.
Publicado: (2010)

catena-Poly[[(2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-cyanido-κ(2) C:N-[(2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thiocyanato-κ(2) S:N]
por: Zhao, Jun, et al.
Publicado: (2008)

Iron arsenides with three-dimensional FeAs layer networks: Ca(n(n+1)/2)(Fe(1−x)Pt(x))((2+3n))Pt(n(n−1)/2)As((n+1)(n+2)/2) (n = 2, 3)
por: Katayama, Naoyuki, et al.
Publicado: (2016)

Poly[μ-4,4′-bipyridine-κ(2) N:N′-μ-thiocyanato-κ(2) N:S-copper(I)]
por: Wriedt, Mario, et al.
Publicado: (2008)

Poly[[bis[μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(4) N,O:N′,O′][μ(2)-N,N′-bis(2-pyridylmethyl)oxalamide-κ(2) N:N′]disilver(I)] bis(trifluoromethanesulfonate)]
por: Arman, Hadi D., et al.
Publicado: (2010)

catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ-thiocyanato-κ(2) N:S-[(1,10-phenanthroline-κ(2) N,N′)copper(I)]-μ-cyanido-κ(2) N:C]
por: Zhao, Jun, et al.
Publicado: (2008)

Poly[bis(μ(2)-1,3-phenylenediamine-κ(2) N:N′)di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-cadmium]
por: Chemli, Rakia, et al.
Publicado: (2013)

Molybdenum‐Mediated N(2)‐Splitting and Functionalization in the Presence of a Coordinated Alkyne
por: Wagner, Hannah K., et al.
Publicado: (2021)

Bis(methanol-1κO)tetra-μ-pyridazine-1:2κ(4) N:N′;2:3κ(4) N:N′-di-μ-thiocyanato-1:2κ(2) N:N;2:3κ(2) N:N-tetrathiocyanato-1κ(2) N,3κ(2) N-trinickel(II) methanol tetrasolvate
por: Wöhlert, Susanne, et al.
Publicado: (2012)

catena-Poly[[(8-aminoquinoline-κ(2) N,N′)cadmium]-di-μ-thiocyanato-κ(2) N:S;κ(2) S:N-[(8-aminoquinoline-κ(2) N,N′)cadmium]-di-μ-chlorido]
por: Xu, Heng, et al.
Publicado: (2011)

Crystal structure of catena-poly[[aqua(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cobalt(II)]-μ-cyanido-κ(2) N:C-[dicyanidoplatinum(II)]-μ-cyanido-κ(2) C:N]
por: White, Frankie, et al.
Publicado: (2014)

Poly[[(μ-2,2′-bipyrimidine-κ(4) N (1),N (1′):N (3),N (3′))(μ-sulfato-κ(2) O:O′)zinc(II)] monohydrate]
por: Oxendine, Aaron, et al.
Publicado: (2010)

catena-Poly[[(2,2′-bipyrimidine-κ(2) N (1),N (1′))diperchloratocopper(II)]-μ-4,4′-bipyridine-κ(2) N:N′]
por: Xu, Wei, et al.
Publicado: (2008)

Bis{μ-N-[(dimethylamino)dimethylsilyl]-2,6-dimethylanilido}-κ(2) N:N′;κ(2) N′:N-dicopper(I)
por: Chen, Juan
Publicado: (2010)

Poly[[(μ(2)-2-amino-4,5-dimethybenzenesulfonato-κ(2) N:O)(μ(2)-2-methylpyrazine-κ(2) N:N′)silver(I)] monohydrate]
por: Dong, Xian-Wu, et al.
Publicado: (2007)

(μ-2-Pyridinealdazine-κ(4) N,N′:N′′,N′′′)bis[bis(N,N-di-n-propyldithiocarbamato-κ(2) S,S′)cadmium(II)]
por: Poplaukhin, Pavel, et al.
Publicado: (2008)

[μ-N,N′-Bis(2-aminoethyl)ethane-1,2-diamine-κ(4) N (1),N (1′):N (2),N (2′)]bis{[N,N′-bis(2-aminoethyl)ethane-1,2-diamine-κ(4) N,N′,N′′,N′′′]cadmium} tetrakis(perchlorate)
por: Goudarziafshar, Hamid, et al.
Publicado: (2012)

Poly[(μ(2)-2-aminopyrimidine-κ(2) N (1):N (3))di-μ(2)-chlorido-mercury(II)]
por: Eshtiagh-Hosseini, Hossein, et al.
Publicado: (2012)

Poly[bis(μ(2)-pyrimidine-κ(2) N:N′)bis(selenocyanato-κN)zinc]
por: Boeckmann, Jan, et al.
Publicado: (2011)

Bis[μ-N-(pyridin-2-yl)methanesulfonamido-κ(2) N:N′]silver(I)
por: Hu, Hui-Ling, et al.
Publicado: (2013)

Poly[bis(μ(3)-thiocyanato-κ(3) N:S:S′)(μ(2)-thiocyanato-κ(2) N:S)(4′-p-tolyl-2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)cadmium(II)silver(I)]
por: Li, Yu-Yang, et al.
Publicado: (2010)

Di-μ-chlorido-bis[chlorido(N,N′-dibenzylpropane-1,2-diamine-κ(2) N,N′)copper(II)]
por: Liu, Yu-Fen, et al.
Publicado: (2009)

catena-Poly[[(5-phenyl-2,2′-bipyridine-κ(2) N,N′)copper(I)]-μ-thiocyanido-κ(2) N:S]
por: Cui, Shuxin, et al.
Publicado: (2012)

Poly[(μ(2)-azido-κ(2) N (1):N (1))[μ(2)-5-(8-quinolyloxymethyl)tetrazolato-κ(4) N (1),O,N (5):N (4)]manganese(II)]
por: Chen, Fang, et al.
Publicado: (2008)

Bis[μ-N-(tert-butyldimethylsilyl)quinolin-8-aminato-1:2κ(2) N (1),N (8):N (8)](N,N,N′,N′-tetramethylethane-1,2-diamine-1κ(2) N,N′)lithiumsodium
por: Chen, Juan, et al.
Publicado: (2012)

N,N′-Dibutyl-N,N,N′,N′-tetramethylethane-1,2-diaminium μ-oxido-bis[trichloridoferrate(III)]
por: Närhi, Sari M., et al.
Publicado: (2012)

Poly[bis(μ-azido-κ(2) N (1):N (1))[μ-1,2-bis(imidazol-1-yl)ethane-κ(2) N (3):N (3′)]cadmium]
por: Li, Hai-Yan, et al.
Publicado: (2012)

catena-Poly[[bis(quinolin-8-amine-κ(2) N,N′)cadmium(II)]-μ-cyanido-κ(2) N:C-[dicyanidonickel(II)]-μ-cyanido-κ(2) C:N]
por: Khelfa, Selma, et al.
Publicado: (2021)

catena-Poly[[(2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)(tricyanomethanido-κN)nickel(II)]-μ-tricyanomethanido]
por: Luo, Jun, et al.
Publicado: (2008)

μ-1,2-Di-4-pyridylethane-κ(2) N:N′-bis[bis(N,N-diisopropyldithiocarbamato-κ(2) S,S′)zinc(II)]
por: Avila, Vanessa, et al.
Publicado: (2008)

catena-Poly[[bis(N-ethylethylenediamine-κ(2) N,N′)copper(II)]-μ-cyanido-κ(2) N:C-[dicyanido-κ(2) C-palladium(II)]-μ-cyanido-κ(2) C:N]
por: Akitsu, Takashiro, et al.
Publicado: (2009)

Syntheses, crystal structures and thermal properties of catena-poly[cadmium(II)-di-μ-bromido-μ-pyridazine-κ(2) N (1):N (2)] and catena-poly[cadmium(II)-di-μ-iodido-μ-pyridazine-κ(2) N (1):N (2)]
por: Näther, Christian, et al.
Publicado: (2023)

Di-μ-chlorido-bis[aqua(2,2′-bipyridine-κ(2) N,N′)chloridocobalt(II)]
por: Zhu, Li-Li, et al.
Publicado: (2009)

Crystal structure of dimethyl-1κ(2) C-bis(μ-4-methylphenolato-1:2κ(2) O:O)(N,N,N′,N′-tetramethylethylenediamine-2κ(2) N,N′)indium(III)lithium(I)
por: Briand, Glen G., et al.
Publicado: (2015)

N-terminal tyrosine of ISCU2 triggers [2Fe-2S] cluster synthesis by ISCU2 dimerization
por: Freibert, Sven-A., et al.
Publicado: (2021)

Poly[[μ-N,N′-bis(2-hydroxyethyl)-N,N,N′,N′-tetramethylpropane-1,3-diaminium-κ(2) O:O′]tetra-μ-bromido-dibromidodimanganese(II)]
por: Rinta, Heikki, et al.
Publicado: (2012)

Poly[(acetonitrile-κN)-μ(3)-thiocyanato-κ(3) N:S:S-μ(2)-thiocyanato-κ(2) N:S-cadmium]
por: Reinert, Thorben, et al.
Publicado: (2013)

Cannot write session to /tmp/vufind_sessions/sess_nfrj43uu1upj71q65ajbe14smf