Triple Regioselective Functionalization of Cationic [4]Helicenes via Iridium‐Catalyzed Borylation and Suzuki Cross‐Coupling Reactivity

In essentially one‐pot, using Ir‐ and Pd‐catalysis, tris(arene)‐functionalized cationic [4]helicenes are synthesized with full regioselectivity and enantiospecificity starting from a trivial precursor (17 examples). This poly‐addition of aryl groups improves key optical properties, that is, fluoresc...

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Detalles Bibliográficos
Autores principales: Frédéric, Lucas, Fabri, Bibiana, Guénée, Laure, Zinna, Francesco, Di Bari, Lorenzo, Lacour, Jérôme
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804708/
https://www.ncbi.nlm.nih.gov/pubmed/35796630
http://dx.doi.org/10.1002/chem.202201853

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804708/
https://www.ncbi.nlm.nih.gov/pubmed/35796630
http://dx.doi.org/10.1002/chem.202201853

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