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Dihydrogen Activation with a Neutral, Intermolecular Silicon(IV)‐Amine Frustrated Lewis Pair

The heterolytic cleavage of dihydrogen constitutes the hallmark reaction of frustrated Lewis pairs (FLP). While being well‐established for planar Lewis acids, such as boranes or silylium ions, the observation of the primary H(2) splitting products with non‐planar Lewis acid FLPs remained elusive. In...

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Detalles Bibliográficos
Autores principales: Thorwart, Thaddäus, Hartmann, Deborah, Greb, Lutz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804801/
https://www.ncbi.nlm.nih.gov/pubmed/35861023
http://dx.doi.org/10.1002/chem.202202273