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Dihydrogen Activation with a Neutral, Intermolecular Silicon(IV)‐Amine Frustrated Lewis Pair
The heterolytic cleavage of dihydrogen constitutes the hallmark reaction of frustrated Lewis pairs (FLP). While being well‐established for planar Lewis acids, such as boranes or silylium ions, the observation of the primary H(2) splitting products with non‐planar Lewis acid FLPs remained elusive. In...
Autores principales: | Thorwart, Thaddäus, Hartmann, Deborah, Greb, Lutz |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804801/ https://www.ncbi.nlm.nih.gov/pubmed/35861023 http://dx.doi.org/10.1002/chem.202202273 |
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