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Two Paths to Oxidative C−H Amination Under Basic Conditions: A Theoretical Case Study Reveals Hidden Opportunities Provided by Electron Upconversion
Traditionally, cross‐dehydrogenative coupling (CDC) leads to C−N bond formation under basic and oxidative conditions and is proposed to proceed via a two‐electron bond formation mediated by carbenium ions. However, the formation of such high‐energy intermediates is only possible in the presence of s...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804812/ https://www.ncbi.nlm.nih.gov/pubmed/35880945 http://dx.doi.org/10.1002/chem.202201637 |