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Acene Size‐Dependent Transition of The Radical Centers From the Metal to The Acene Parts In Monocationic Dinuclear (Diethynylacene)diyl Complexes
Controlling radical localization/delocalization is important for functional materials. The present paper describes synthesis and results of electrochemical, spectroscopic, and theoretical studies of diruthenium (p‐diethynylacene)diyl complexes, Me(3)Si‐(C≡C)(2)‐Ru(dppe)(2)‐C≡C−Ar‐C≡C−Ru(dppe)(2)‐(C≡...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804824/ https://www.ncbi.nlm.nih.gov/pubmed/35680560 http://dx.doi.org/10.1002/chem.202201358 |