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Homolytic N−S Bond Cleavage in Vinyl Triflimides Enabled by Triplet–Triplet Energy Transfer

Vinyl triflimides are a new compound class with unknown reactivity. A computational analysis identified homolytic cleavage of the N−Tf bond induced by triplet–triplet energy transfer (EnT) as a highly interesting reaction type that might be accessible. A combination of experimental and mechanistic w...

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Detalles Bibliográficos
Autores principales: Strauch, Christina, Schroeder, Sebastian, Grelier, Gwendal, Niggemann, Meike
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804857/
https://www.ncbi.nlm.nih.gov/pubmed/35793203
http://dx.doi.org/10.1002/chem.202201830