Quantification of the Electrophilicities of Diazoalkanes: Kinetics and Mechanism of Azo Couplings with Enamines and Sulfonium Ylides

Kinetics and mechanism of the reactions of methyl diazoacetate, dimethyl diazomalonate, 4‐nitrophenyldiazomethane, and diphenyldiazomethane with sulfonium ylides and enamines were investigated by UV‐Vis and NMR spectroscopy. Ordinary alkenes undergo 1,3‐dipolar cycloadditions with these diazo compou...

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Detalles Bibliográficos
Autores principales: Li, Le, Mayer, Robert J., Stephenson, David S., Mayer, Peter, Ofial, Armin R., Mayr, Herbert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804914/
https://www.ncbi.nlm.nih.gov/pubmed/35758555
http://dx.doi.org/10.1002/chem.202201376

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804914/
https://www.ncbi.nlm.nih.gov/pubmed/35758555
http://dx.doi.org/10.1002/chem.202201376

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