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Quantification of the Electrophilicities of Diazoalkanes: Kinetics and Mechanism of Azo Couplings with Enamines and Sulfonium Ylides
Kinetics and mechanism of the reactions of methyl diazoacetate, dimethyl diazomalonate, 4‐nitrophenyldiazomethane, and diphenyldiazomethane with sulfonium ylides and enamines were investigated by UV‐Vis and NMR spectroscopy. Ordinary alkenes undergo 1,3‐dipolar cycloadditions with these diazo compou...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9804914/ https://www.ncbi.nlm.nih.gov/pubmed/35758555 http://dx.doi.org/10.1002/chem.202201376 |