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Bismuth‐Mediated α‐Arylation of Acidic Diketones with ortho‐Substituted Boronic Acids

The α‐arylation of cyclic and fluoroalkyl 1,3‐diketones is made challenging by the highly stabilized nature of the corresponding enolates, and is especially difficult for sterically demanding aryl partners. As a general solution to this problem, we report the Bi‐mediated oxidative coupling of acidic...

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Detalles Bibliográficos
Autores principales: Ruffell, Katie, Argent, Stephen P., Ling, Kenneth B., Ball, Liam T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805042/
https://www.ncbi.nlm.nih.gov/pubmed/35950691
http://dx.doi.org/10.1002/anie.202210840