Synthesis, Structure and Reactivity of a Cyapho(dicyano)methanide Salt

We describe the synthesis of a cyapho(dicyano)methanide salt, [K(18‐crown‐6)][C(CN)(2)(CP)], from reaction of [Na(18‐crown‐6)][PH(2)] (18‐crown‐6=1,4,7,10,13,16‐hexaoxacyclooctadecane) with 1,1‐diethoxy‐2,2‐dicyanoethylene (EtO)(2)C=C(CN)(2). The reaction proceeds through a Michael addition‐eliminat...

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Detalles Bibliográficos
Autores principales: Hu, Chenyang, Goicoechea, Jose M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805078/
https://www.ncbi.nlm.nih.gov/pubmed/35876032
http://dx.doi.org/10.1002/anie.202208921

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805078/
https://www.ncbi.nlm.nih.gov/pubmed/35876032
http://dx.doi.org/10.1002/anie.202208921

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