Cargando…

Synthesis, Structure and Reactivity of a Cyapho(dicyano)methanide Salt

We describe the synthesis of a cyapho(dicyano)methanide salt, [K(18‐crown‐6)][C(CN)(2)(CP)], from reaction of [Na(18‐crown‐6)][PH(2)] (18‐crown‐6=1,4,7,10,13,16‐hexaoxacyclooctadecane) with 1,1‐diethoxy‐2,2‐dicyanoethylene (EtO)(2)C=C(CN)(2). The reaction proceeds through a Michael addition‐eliminat...

Descripción completa

Detalles Bibliográficos
Autores principales:	Hu, Chenyang, Goicoechea, Jose M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805078/ https://www.ncbi.nlm.nih.gov/pubmed/35876032 http://dx.doi.org/10.1002/anie.202208921

Ejemplares similares

The 2‐Arsaethynolate Anion: Synthesis and Reactivity Towards Heteroallenes
por: Hinz, Alexander, et al.
Publicado: (2016)

1,5-Dicyanoanthraquinone
por: Armaghan, Mahsa, et al.
Publicado: (2010)

Synthesis of ferrocenyl-substituted 1,3-dithiolanes via [3 + 2]-cycloadditions of ferrocenyl hetaryl thioketones with thiocarbonyl S-methanides
por: Mlostoń, Grzegorz, et al.
Publicado: (2016)

Bis(2,2′:6′,2′′-terpyridine)cobalt(II) bis(tricyanomethanide)
por: Luo, Jun, et al.
Publicado: (2009)

Electronic nature of zwitterionic alkali metal methanides, silanides and germanides – a combined experimental and computational approach
por: Li, H., et al.
Publicado: (2017)

Dimerization reactions of aryl selenophen-2-yl-substituted thiocarbonyl S-methanides as diradical processes: a computational study
por: McKee, Michael L, et al.
Publicado: (2017)

Tris(5,6-dimethyl-1,10-phenanthroline-κ(2) N,N′)iron(II) bis(tricyanomethanide)
por: Váhovská, Lucia, et al.
Publicado: (2012)

Synthesis of Anionic Phosphorus-Containing Heterocycles by Intramolecular Cyclizations Involving N-Functionalized Phosphinecarboxamides
por: Robinson, Thomas P, et al.
Publicado: (2015)

Structures, Photoresponse Properties, and Biological Activity of Dicyano-Substituted 4-Aryl-2-pyridone Derivatives
por: Mandal, Tripti, et al.
Publicado: (2019)

Subphthalocyaninato Boron(III) Hydride: Synthesis, Structure and Reactivity
por: Tejerina, Lara, et al.
Publicado: (2021)

(Nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)copper(II) tricyanomethanide
por: Lacková, Katarína, et al.
Publicado: (2012)

Crystal structure of a compact three-dimensional metal–organic framework based on Cs(+) and (4,5-dicyano-1,2-phenylene)bis(phosphonic acid)
por: Mendes, Ricardo F., et al.
Publicado: (2016)

Dicyano- and tetracyanopentacene: foundation of an intriguing new class of easy-to-synthesize organic semiconductors
por: Glöcklhofer, Florian, et al.
Publicado: (2017)

Electro-organic green synthesis of dicyano-2-(2-oxoindolin-3-ylidene) malononitriles using molecular iodine as catalyst
por: Verma, Neetu, et al.
Publicado: (2023)

9-(Dicyanomethylidene)fluorene–tetrathiafulvalene (1/1)
por: Salmerón-Valverde, Amparo, et al.
Publicado: (2012)

Solid-State Highly Efficient DR Mono and Poly-dicyano-phenylenevinylene Fluorophores
por: Panunzi, Barbara, et al.
Publicado: (2018)

[(3-Methylphenyl)(triphenylphosphonio)methanide-κC]triphenylphosphorane}(pentafluorophenyl-κC)gold(I) diethyl ether solvate
por: Strasser, Christoph E., et al.
Publicado: (2009)

Synthesis and reactivity of azole-based iodazinium salts
por: Kuczmera, Thomas J, et al.
Publicado: (2023)

Dimethyl 6,6′-dicyano-2,2′-bipyridine-3,3′-dicarboxylate
por: He, Xiao, et al.
Publicado: (2009)

Crystal structures of (1,4,7,10-tetraazacyclododecane-κ(4) N)bis(tricyanomethanido-κN)nickel and (1,4,7,10-tetraazacyclododecane-κ(4) N)(tricyanomethanido-κN)copper tricyanomethanide
por: Luo, Jun, et al.
Publicado: (2015)

Transient [3,3] Cope rearrangement of 3,3-dicyano-1,5-dienes: computational analysis and 2-step synthesis of arylcycloheptanes
por: Fereyduni, Ehsan, et al.
Publicado: (2018)

4,5-Dicyano-1,2,3-Triazole—A Promising Precursor for a New Family of Energetic Compounds and Its Nitrogen-Rich Derivatives: Synthesis and Crystal Structures
por: Cao, Wenli, et al.
Publicado: (2021)

One-Pot Synthesis and Applications of N-Heteroaryl Iodonium Salts
por: Bielawski, Marcin, et al.
Publicado: (2014)

Synthesis and Characterization of Stable Iron Pentacarbonyl Radical Cation Salts
por: Rall, Jan M., et al.
Publicado: (2022)

Exploiting the Brønsted Acidity of Phosphinecarboxamides for the Synthesis of New Phosphides and Phosphines
por: Jupp, Andrew R, et al.
Publicado: (2015)

Tetraethylammonium 7,12-dicyano-1-carba-closo-dodecaborate
por: Juhasz, Marcus A., et al.
Publicado: (2014)

Synthesis of Monolithic Potassium Geopolymer Ceramics Assisted by Molten Salt
por: Ai, Tao, et al.
Publicado: (2019)

Pyrimidin‐6‐yl Trifluoroborate Salts as Versatile Templates for Heterocycle Synthesis
por: Cousins, David L., et al.
Publicado: (2021)

Novel Dicyano-Phenylenevinylene Fluorophores for Low-Doped Layers: A Highly Emissive Material for Red OLEDs
por: Diana, Rosita, et al.
Publicado: (2019)

Revealing the Role of the Cyaphide Ion as a Bridging Ligand in Heterometallic Complexes
por: Yang, Eric S., et al.
Publicado: (2022)

Crystal structure and Hirshfeld surface analysis of methyl 4′-amino-3′,5′-dicyano-2,2′′-dioxodispiro[indoline-3,1′-cyclopentane-2′,3′′-indolin]-3′-ene-5′-carboximidate with an unknown solvent
por: Naghiyev, Farid N., et al.
Publicado: (2022)

A Monoanionic Arsenide Source: Decarbonylation of the 2‐Arsaethynolate Anion upon Reaction with Bulky Stannylenes
por: Hinz, Alexander, et al.
Publicado: (2016)

Synthesis and Antimicrobial Evaluation of Bis‐morpholine Triazine Quaternary Ammonium Salts
por: Morandini, Andrea, et al.
Publicado: (2021)

Dimethyl 3,3′-[(4,5-dicyano-1,2-phenylene)bis(oxy)]dibenzoate
por: Bai, Ming, et al.
Publicado: (2012)

Ca(IO(3))(2) nanoparticles: fabrication and application as an eco-friendly and recyclable catalyst for the green synthesis of quinoxalines, pyridopyrazines, and 2,3-dicyano pyrazines
por: Kalhor, Mehdi, et al.
Publicado: (2022)

Synthesis and Ambiphilic Reactivity of Metalated Diorgano‐Phosphonite Boranes
por: Hettich, Thomas D., et al.
Publicado: (2021)

4,4′-Dicyano- versus 4,4′-Difluoro-BODIPYs in Chemoselective Postfunctionalization Reactions: Synthetic Advantages and Applications
por: Ventura, Juan, et al.
Publicado: (2023)

Synthesis of Poly (2-Acrylamido-2-methylpropanesulfnoinc Salt) Modified Carbon Spheres
por: Su, Na
Publicado: (2023)

A Mild Synthesis of Bicyclic Alkoxyoxazolium Salts from Proline and Pipecolic Acid Derivatives
por: Spinozzi, Eleonora, et al.
Publicado: (2019)

Formation, Reactivity and Decomposition of Aryl Phospha‐Enolates
por: Urwin, Stephanie J., et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_bqdm4olgsd20t0thcs2qt2dnhv