Stereoselective Activation of Small Molecules by a Stable Chiral Silene

The reaction of the dilithium salt of the enantiopure (S)‐BINOL (1,1’‐bi‐2‐naphthol) with two equivalents of the amidinate‐stabilized chlorosilylene [L(Ph)SiCl] (L(Ph)=PhC(NtBu)(2)) led to the formation of the first example of a chiral cyclic silene species comprising an (S)‐BINOL ligand. The reacti...

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Detalles Bibliográficos
Autores principales: Sun, Xiaofei, Hinz, Alexander, Kucher, Hannes, Gamer, Michael T., Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805157/
https://www.ncbi.nlm.nih.gov/pubmed/35762907
http://dx.doi.org/10.1002/chem.202201963

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805157/
https://www.ncbi.nlm.nih.gov/pubmed/35762907
http://dx.doi.org/10.1002/chem.202201963

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