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Stereoselective Activation of Small Molecules by a Stable Chiral Silene
The reaction of the dilithium salt of the enantiopure (S)‐BINOL (1,1’‐bi‐2‐naphthol) with two equivalents of the amidinate‐stabilized chlorosilylene [L(Ph)SiCl] (L(Ph)=PhC(NtBu)(2)) led to the formation of the first example of a chiral cyclic silene species comprising an (S)‐BINOL ligand. The reacti...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805157/ https://www.ncbi.nlm.nih.gov/pubmed/35762907 http://dx.doi.org/10.1002/chem.202201963 |