Cargando…
Mechanistic Insights about the Ligand‐Enabled Oxy‐arylation/vinylation of Alkenes via Au(I)/Au(III) Catalysis
The mechanism of oxy‐arylation/vinylation of alkenes catalyzed by the (MeDalphos)AuCl complex was comprehensively investigated by DFT. (P,N)Au(Ph)(2+) and (P,N)Au(vinyl)(2+) are key intermediates accounting for the activation of the alkenols and for their cyclization by outer‐sphere nucleophilic att...
| Autores principales: | , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9805180/ https://www.ncbi.nlm.nih.gov/pubmed/35876716 http://dx.doi.org/10.1002/chem.202202110 |