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Observation and Modeling of a Sharp Oxygen Threshold in Aqueous Free Radical and RAFT Polymerization
[Image: see text] It is known that oxygen (O(2)) stops radical polymerization (RP). Here, it was found that the reaction turn-off occurs abruptly at a threshold concentration of O(2), [O(2)](t), for both free RP and reversible addition–fragmentation chain-transfer polymerization (RAFT). In some reac...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2022
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9806832/ https://www.ncbi.nlm.nih.gov/pubmed/36520675 http://dx.doi.org/10.1021/acs.jpcb.2c06067 |