Cargando…
Application of Lithiation–Borylation to the Total Synthesis of (−)-Rakicidin F
[Image: see text] The stereochemistry of the lipophilic side chain of (+)-rakicidin F had not been determined until recently. Using our lithiation–borylation methodology (“assembly line synthesis”) we were able to efficiently prepare the all-syn isomer as well as the C-21 epimer of the side chain, a...
| Autores principales: | , , , , |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
|
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9806854/ https://www.ncbi.nlm.nih.gov/pubmed/36538642 http://dx.doi.org/10.1021/acs.orglett.2c03716 |