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N-oxide ligands for selective separations of lanthanides: insights from computation
Preorganized ligands such as bis-lactam-1,10-phenanthroline (BLPhen) show unique selectivity trends across the lanthanide series, indicating the synergistic effects of both N and O donors in complexing with lanthanides. We hypothesize that by replacing amide functional groups with an N-oxide functio...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9809209/ https://www.ncbi.nlm.nih.gov/pubmed/36686929 http://dx.doi.org/10.1039/d2ra07029d |