Silver-catalyzed direct selanylation of indoles: synthesis and mechanistic insights

Herein we describe the Ag(i)-catalyzed direct selanylation of indoles with diorganoyl diselenides. The reaction gave 3-selanylindoles with high regioselectivity and also allowed direct access to 2-selanylindoles when the C3 position of the indole ring was blocked via a process similar to Plancher re...

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Detalles Bibliográficos
Autores principales: Rios, Elise Ane Maluf, Gomes, Carla M. B., Silvério, Gabriel L., Luz, Eduardo Q., Ali, Sher, D'Oca, Caroline da Ros Montes, Albach, Breidi, Campos, Renan B., Rampon, Daniel S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811358/
https://www.ncbi.nlm.nih.gov/pubmed/36686957
http://dx.doi.org/10.1039/d2ra06813c

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811358/
https://www.ncbi.nlm.nih.gov/pubmed/36686957
http://dx.doi.org/10.1039/d2ra06813c

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