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Experimental assignment of long-range magnetic communication through Pd & Pt metallophilic contacts

Record-breaking magnetic exchange interactions have previously been reported for 3d-metal dimers of the form [M(Pt(SAc)(4))(pyNO(2))](2) (M = Ni or Co) that are linked in the solid state via metallophilic Pt⋯Pt bridges. This contrasts the terminally capped monomers [M(Pt(SAc)(4))(py)(2)], for which...

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Detalles Bibliográficos
Autores principales: Larsen, Emil M. H., Bonde, Niels A., Weihe, Høgni, Ollivier, Jacques, Vosch, Tom, Lohmiller, Thomas, Holldack, Karsten, Schnegg, Alexander, Perfetti, Mauro, Bendix, Jesper
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811497/
https://www.ncbi.nlm.nih.gov/pubmed/36687355
http://dx.doi.org/10.1039/d2sc05201f