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μ-Oxo-bis[(octacosafluoro-meso-tetraphenylporphyrinato)iron(iii)] – synthesis, crystal structure, and catalytic activity in oxidation reactions

We describe the synthesis and X-ray crystal structure of μ-oxo-bis[(octacosafluoro-meso-tetraphenylporphyrinato)iron(iii)] [(FeTPPF(28))(2)O]. This novel iron complex is an efficient catalyst for oxidative biaryl coupling reactions of diarylamines and carbazoles. The asymmetric oxidative coupling in...

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Detalles Bibliográficos
Autores principales: Schuh, Tristan, Kataeva, Olga, Knölker, Hans-Joachim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811517/
https://www.ncbi.nlm.nih.gov/pubmed/36687339
http://dx.doi.org/10.1039/d2sc06083c