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Insights into the thermodynamic–kinetic synergistic separation of propyne/propylene in anion pillared cage MOFs with entropy–enthalpy balanced adsorption sites
Propyne/propylene (C(3)H(4)/C(3)H(6)) separation is an important industrial process yet challenged by the trade-off of selectivity and capacity due to the molecular similarity. Herein, record C(3)H(4)/C(3)H(6) separation performance is achieved by fine tuning the pore structure in anion pillared MOF...
Autores principales: | , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9811657/ https://www.ncbi.nlm.nih.gov/pubmed/36687342 http://dx.doi.org/10.1039/d2sc05742e |