Fe(III) in the high-spin state in di­methyl­ammonium bis­[3-eth­oxy­salicyl­aldehyde thio­semi­car­ba­zon­ato(2–)-κ(3) O (2),N (1),S]ferrate(III)

The synthesis and crystal structure (100 K) of the title com­pound, [(CH(3))(2)NH(2)][Fe(C(10)H(11)O(2)N(3)S)(2)], are reported. The asymmetric unit consists of an octa­hedral [Fe(III)(L)(2)](−) fragment, where L (2−) is 3-eth­oxy­salicyl­aldehyde thio­semi­car­ba­zon­ate(2−), and a di­methyl­ammoni...

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Detalles Bibliográficos
Autores principales: Powell, Robyn E., Lees, Martin R., Tizzard, Graham J., Coles, Simon J., Yuan, Qingchun, van Koningsbruggen, Petra J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9813924/
https://www.ncbi.nlm.nih.gov/pubmed/36602017
http://dx.doi.org/10.1107/S2053229622011597

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9813924/
https://www.ncbi.nlm.nih.gov/pubmed/36602017
http://dx.doi.org/10.1107/S2053229622011597

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