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Structure and charge analysis of a cyclic aluminium hydride: cyclo-1,5-bis-μ-dimethylamino-3,7-di-μ-hydrido-2,4,6,8-tetrakis(dimethylaluminium)
The title compound, [Al(4)(CH(3))(8)(C(2)H(7)N)(2)H(2)], crystallizes as eight-membered rings with –(CH(3))(2)Al–(CH(3))(2)N–(CH(3))(2)Al– moieties connected by single hydride bridges. In the X-ray structure, the ring has a chair conformation, with the hydride H atoms being close to the plane thr...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9813926/ https://www.ncbi.nlm.nih.gov/pubmed/36602016 http://dx.doi.org/10.1107/S2053229622011391 |