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Structure and charge analysis of a cyclic alu­minium hy­dride: cyclo-1,5-bis-μ-di­methyl­amino-3,7-di-μ-hy­drido-2,4,6,8-tetra­kis­(di­methyl­alu­minium)

The title com­pound, [Al(4)(CH(3))(8)(C(2)H(7)N)(2)H(2)], crystallizes as eight-membered rings with –(CH(3))(2)Al–(CH(3))(2)N–(CH(3))(2)Al– moieties connected by single hy­dride bridges. In the X-ray structure, the ring has a chair conformation, with the hy­dride H atoms being close to the plane thr...

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Detalles Bibliográficos
Autores principales: Corfield, Peter W. R., Schrier, Joshua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9813926/
https://www.ncbi.nlm.nih.gov/pubmed/36602016
http://dx.doi.org/10.1107/S2053229622011391