Diels–Alder reactions and electrophilic substitutions with atypical regioselectivity enable functionalization of terminal rings of anthracene

Reversing the regioselectivity of the renowned Diels–Alder reaction by overriding the usual thermodynamic and kinetic governing factors has always been a formidable challenge to synthetic organic chemists. Anthracenes are well-known to undergo [4 + 2]-cycloadditions with dienophiles at their 9,10-po...

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Detalles Bibliográficos
Autores principales: Huynh, Vinh Ngoc, Leitner, Michael, Bhattacharyya, Aditya, Uhlstein, Lisa, Kreitmeier, Peter, Sakrausky, Patrick, Rehbein, Julia, Reiser, Oliver
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814106/
https://www.ncbi.nlm.nih.gov/pubmed/36703384
http://dx.doi.org/10.1038/s42004-020-00407-9

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814106/
https://www.ncbi.nlm.nih.gov/pubmed/36703384
http://dx.doi.org/10.1038/s42004-020-00407-9

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