Air-stable 18-electron adducts of Schrock catalysts with tuned stability constants for spontaneous release of the active species

Schrock alkylidenes are highly versatile, very active olefin metathesis catalysts, but their pronounced sensitivity to air still hinders their applications. Converting them into more robust but inactive 18-electron adducts was suggested previously to facilitate their handling. Generating the active...

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Detalles Bibliográficos
Autores principales: Gulyás, Henrik, Hayano, Shigetaka, Madarász, Ádám, Pápai, Imre, Szabó, Márk, Bucsai, Ágota, Martin, Eddy, Benet-Buchholz, Jordi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814263/
https://www.ncbi.nlm.nih.gov/pubmed/36697610
http://dx.doi.org/10.1038/s42004-021-00503-4

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814263/
https://www.ncbi.nlm.nih.gov/pubmed/36697610
http://dx.doi.org/10.1038/s42004-021-00503-4

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