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Air-stable 18-electron adducts of Schrock catalysts with tuned stability constants for spontaneous release of the active species
Schrock alkylidenes are highly versatile, very active olefin metathesis catalysts, but their pronounced sensitivity to air still hinders their applications. Converting them into more robust but inactive 18-electron adducts was suggested previously to facilitate their handling. Generating the active...
Autores principales: | Gulyás, Henrik, Hayano, Shigetaka, Madarász, Ádám, Pápai, Imre, Szabó, Márk, Bucsai, Ágota, Martin, Eddy, Benet-Buchholz, Jordi |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2021
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814263/ https://www.ncbi.nlm.nih.gov/pubmed/36697610 http://dx.doi.org/10.1038/s42004-021-00503-4 |
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