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Pd-catalyzed access to mono- and di-fluoroallylic amines from primary anilines
The Pd-catalyzed highly selective synthesis of mono- and di-2-fluoroallylic amines from gem-difluorocyclopropanes and ubiquitous unprotected primary anilines is herein described. Initial kinetic investigations suggest a first order in the gem-difluorocyclopropane substrate, as well as a circa zeroth...
Autores principales: | Wang, Xingben, Patureau, Frederic W. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814328/ https://www.ncbi.nlm.nih.gov/pubmed/36530134 http://dx.doi.org/10.1039/d2cc05844h |
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