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Applying the Jellium model to octacarbonyl metal complexes
The recently reported octacarbonyl metal complexes M(CO)(8) (M = Ca, Sr, Ba) feature interesting bonding structures. In these compounds, the bond order is 7, while accommodating 8 lone pairs of ligands in forming octa-coordinated complexes or ions. Here, by comparing [Ba(CO)(8)](2−) and metal cluste...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814474/ https://www.ncbi.nlm.nih.gov/pubmed/36703452 http://dx.doi.org/10.1038/s42004-020-0285-2 |