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Nickel-aluminium pincer complexes undergo cooperative bond activation

Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity.

Detalles Bibliográficos
Autor principal: Bissette, Andrew J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814506/
https://www.ncbi.nlm.nih.gov/pubmed/36697802
http://dx.doi.org/10.1038/s42004-021-00519-w