Cargando…
Nickel-aluminium pincer complexes undergo cooperative bond activation
Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity.
| Autor principal: | |
|---|---|
| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2021
|
| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814506/ https://www.ncbi.nlm.nih.gov/pubmed/36697802 http://dx.doi.org/10.1038/s42004-021-00519-w |
| _version_ | 1784864149443969024 |
|---|---|
| author | Bissette, Andrew J. |
| author_facet | Bissette, Andrew J. |
| author_sort | Bissette, Andrew J. |
| collection | PubMed |
| description | Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity. |
| format | Online Article Text |
| id | pubmed-9814506 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2021 |
| publisher | Nature Publishing Group UK |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-98145062023-01-10 Nickel-aluminium pincer complexes undergo cooperative bond activation Bissette, Andrew J. Commun Chem Research Highlight Lewis acid additives such as aluminium can enable fascinating new reactivity in transition metal catalysts, but few catalytic intermediates have been characterised. Now, a nickel-aluminium pincer complex offers new mechanistic insight into transmetalation, and new potential for reactivity. Nature Publishing Group UK 2021-05-27 /pmc/articles/PMC9814506/ /pubmed/36697802 http://dx.doi.org/10.1038/s42004-021-00519-w Text en © Springer Nature Limited 2021 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
| spellingShingle | Research Highlight Bissette, Andrew J. Nickel-aluminium pincer complexes undergo cooperative bond activation |
| title | Nickel-aluminium pincer complexes undergo cooperative bond activation |
| title_full | Nickel-aluminium pincer complexes undergo cooperative bond activation |
| title_fullStr | Nickel-aluminium pincer complexes undergo cooperative bond activation |
| title_full_unstemmed | Nickel-aluminium pincer complexes undergo cooperative bond activation |
| title_short | Nickel-aluminium pincer complexes undergo cooperative bond activation |
| title_sort | nickel-aluminium pincer complexes undergo cooperative bond activation |
| topic | Research Highlight |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814506/ https://www.ncbi.nlm.nih.gov/pubmed/36697802 http://dx.doi.org/10.1038/s42004-021-00519-w |
| work_keys_str_mv | AT bissetteandrewj nickelaluminiumpincercomplexesundergocooperativebondactivation |