Diverse reactivity of the gem-difluorovinyl iodonium salt for direct incorporation of the difluoroethylene group into N- and O-nucleophiles

The synthesis of gem-difluoroethylene compounds remains a difficult task in organic synthesis. Here, the direct difluoroethylation reactions of N- and O-nucleophiles including amides and acids were realized with a hypervalent iodine reagent: gem-difluorovinyl iodonium salt (DFVI). The reactions were...

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Detalles Bibliográficos
Autores principales: Ge, Chenxin, Wang, Bin, Jiang, Yunchen, Chen, Chao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814539/
https://www.ncbi.nlm.nih.gov/pubmed/36697903
http://dx.doi.org/10.1038/s42004-022-00772-7

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814539/
https://www.ncbi.nlm.nih.gov/pubmed/36697903
http://dx.doi.org/10.1038/s42004-022-00772-7

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