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Construction of poly-N-heterocyclic scaffolds via the controlled reactivity of Cu-allenylidene intermediates

Controlling the sequence of the three consecutive reactive carbon centres of Cu-allenylidene remains a challenge. One of the impressive achievements in this area is the Cu-catalyzed annulation of 4-ethynyl benzoxazinanones, which are transformed into zwitterionic Cu-stabilized allenylidenes that are...

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Detalles Bibliográficos
Autores principales: Gannarapu, Malla Reddy, Imai, Takanori, Iwaki, Kentaro, Tsuzuki, Seiji, Shibata, Norio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2021
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814594/
https://www.ncbi.nlm.nih.gov/pubmed/36697740
http://dx.doi.org/10.1038/s42004-021-00596-x