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Highly congested spiro-compounds via photoredox-mediated dearomative annulation cascade

Photo-mediated radical dearomatization involving 5-exo-trig cyclizations has proven to be an important route to accessing spirocyclic compounds, whereas 6-exo-trig spirocyclization has been much less explored. In this work, a dearomative annulation cascade is realized through photoredox-mediated C–O...

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Detalles Bibliográficos
Autores principales: Zhou, Chao, Shatskiy, Andrey, Temerdashev, Azamat Z., Kärkäs, Markus D., Dinér, Peter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9814605/
https://www.ncbi.nlm.nih.gov/pubmed/36697909
http://dx.doi.org/10.1038/s42004-022-00706-3